Bioinspired CS@PAN Electrospun Fibrous Aerogels with Vertical Capsule Vessels for Self-Feedback Temperature Sensing

Xianghui Kong; Yue Li; Lifan Shen; Jianming An; Edwin Yue Bun Pun; Hai Lin

doi:10.1021/acsaelm.2c00765

Bioinspired CS@PAN Electrospun Fibrous Aerogels with Vertical Capsule Vessels for Self-Feedback Temperature Sensing

Xianghui Kong
, Yue Li
, Lifan Shen^*
, Jianming An
, Edwin Yue Bun Pun
, Hai Lin^*

^*Corresponding author for this work

Dalian Polytechnic University
City University of Hong Kong
Beijing University of Technology

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Unconventional sensors with characteristics of portability, safety, remote manipulation, and high spatiotemproal resolution are highly desirable to detect varied temperature under specific conditions such as local temperature fields of the microenvironment. Herein, a 3D high-performance optical thermometry platform driven by the up-conversion green fluorescence of Er³⁺/Yb³⁺co-doped electrospun fibrous aerogels is developed. The system simply consists of polycrystalline-encapsulated (Y_1-x-yEr_xYb_y)₂O₂S/polyacrylonitrile (YOS-EY/PAN) electrospun fibers and chitosan (CS). The flexible fibers form a hierarchically ordered bionic cellular structure through bio-based cross-linking, which avoids toxic chemical cross-linking. Additionally, the intense green emission is ascribed to ²H_11/2/⁴S_3/2→ ⁴I_15/2transitions, as the main indicator to determine the relative sensitivity of 1.22% K^-1at 303 K. More importantly, multipoint dispersed lanthanide (Ln) between cell walls confers stronger temperature sensing capability to aerogels. The successful strategy provides insights for the development of luminescence thermometry and opens a window for multidimensional temperature sensing.

Original language	English
Pages (from-to)	3714-3723
Number of pages	10
Journal	ACS Applied Electronic Materials
Volume	4
Issue number	7
DOIs	https://doi.org/10.1021/acsaelm.2c00765
State	Published - 26 Jul 2022
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 12 Responsible Consumption and Production

Keywords

(YErY)OS/polyacrylonitrile
capsule space
electrospun fibrous aerogels
fluorescence intensity ratio
optical temperature sensing

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10.1021/acsaelm.2c00765

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@article{e83555fd8b2648d78bcb1eb82c7351dc,

title = "Bioinspired CS@PAN Electrospun Fibrous Aerogels with Vertical Capsule Vessels for Self-Feedback Temperature Sensing",

abstract = "Unconventional sensors with characteristics of portability, safety, remote manipulation, and high spatiotemproal resolution are highly desirable to detect varied temperature under specific conditions such as local temperature fields of the microenvironment. Herein, a 3D high-performance optical thermometry platform driven by the up-conversion green fluorescence of Er3+/Yb3+co-doped electrospun fibrous aerogels is developed. The system simply consists of polycrystalline-encapsulated (Y1-x-yErxYby)2O2S/polyacrylonitrile (YOS-EY/PAN) electrospun fibers and chitosan (CS). The flexible fibers form a hierarchically ordered bionic cellular structure through bio-based cross-linking, which avoids toxic chemical cross-linking. Additionally, the intense green emission is ascribed to 2H11/2/4S3/2→ 4I15/2transitions, as the main indicator to determine the relative sensitivity of 1.22\% K-1at 303 K. More importantly, multipoint dispersed lanthanide (Ln) between cell walls confers stronger temperature sensing capability to aerogels. The successful strategy provides insights for the development of luminescence thermometry and opens a window for multidimensional temperature sensing.",

keywords = "(YErY)OS/polyacrylonitrile, capsule space, electrospun fibrous aerogels, fluorescence intensity ratio, optical temperature sensing",

author = "Xianghui Kong and Yue Li and Lifan Shen and Jianming An and Pun, \{Edwin Yue Bun\} and Hai Lin",

year = "2022",

month = jul,

day = "26",

doi = "10.1021/acsaelm.2c00765",

language = "英语",

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issn = "2637-6113",

publisher = "American Chemical Society",

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}

TY - JOUR

T1 - Bioinspired CS@PAN Electrospun Fibrous Aerogels with Vertical Capsule Vessels for Self-Feedback Temperature Sensing

AU - Kong, Xianghui

AU - Li, Yue

AU - Shen, Lifan

AU - An, Jianming

AU - Pun, Edwin Yue Bun

AU - Lin, Hai

PY - 2022/7/26

Y1 - 2022/7/26

N2 - Unconventional sensors with characteristics of portability, safety, remote manipulation, and high spatiotemproal resolution are highly desirable to detect varied temperature under specific conditions such as local temperature fields of the microenvironment. Herein, a 3D high-performance optical thermometry platform driven by the up-conversion green fluorescence of Er3+/Yb3+co-doped electrospun fibrous aerogels is developed. The system simply consists of polycrystalline-encapsulated (Y1-x-yErxYby)2O2S/polyacrylonitrile (YOS-EY/PAN) electrospun fibers and chitosan (CS). The flexible fibers form a hierarchically ordered bionic cellular structure through bio-based cross-linking, which avoids toxic chemical cross-linking. Additionally, the intense green emission is ascribed to 2H11/2/4S3/2→ 4I15/2transitions, as the main indicator to determine the relative sensitivity of 1.22% K-1at 303 K. More importantly, multipoint dispersed lanthanide (Ln) between cell walls confers stronger temperature sensing capability to aerogels. The successful strategy provides insights for the development of luminescence thermometry and opens a window for multidimensional temperature sensing.

AB - Unconventional sensors with characteristics of portability, safety, remote manipulation, and high spatiotemproal resolution are highly desirable to detect varied temperature under specific conditions such as local temperature fields of the microenvironment. Herein, a 3D high-performance optical thermometry platform driven by the up-conversion green fluorescence of Er3+/Yb3+co-doped electrospun fibrous aerogels is developed. The system simply consists of polycrystalline-encapsulated (Y1-x-yErxYby)2O2S/polyacrylonitrile (YOS-EY/PAN) electrospun fibers and chitosan (CS). The flexible fibers form a hierarchically ordered bionic cellular structure through bio-based cross-linking, which avoids toxic chemical cross-linking. Additionally, the intense green emission is ascribed to 2H11/2/4S3/2→ 4I15/2transitions, as the main indicator to determine the relative sensitivity of 1.22% K-1at 303 K. More importantly, multipoint dispersed lanthanide (Ln) between cell walls confers stronger temperature sensing capability to aerogels. The successful strategy provides insights for the development of luminescence thermometry and opens a window for multidimensional temperature sensing.

KW - (YErY)OS/polyacrylonitrile

KW - capsule space

KW - electrospun fibrous aerogels

KW - fluorescence intensity ratio

KW - optical temperature sensing

UR - https://www.scopus.com/pages/publications/85136071798

U2 - 10.1021/acsaelm.2c00765

DO - 10.1021/acsaelm.2c00765

M3 - 文章

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SN - 2637-6113

VL - 4

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EP - 3723

JO - ACS Applied Electronic Materials

JF - ACS Applied Electronic Materials

IS - 7

ER -

Bioinspired CS@PAN Electrospun Fibrous Aerogels with Vertical Capsule Vessels for Self-Feedback Temperature Sensing

Abstract

UN SDGs

Keywords

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