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Brillouin study of acoustic phonon confinement in Ge O2 nanocubes

  • Y. Li
  • , H. S. Lim
  • , S. C. Ng
  • , M. H. Kuok*
  • , M. Y. Ge
  • , J. Z. Jiang
  • *Corresponding author for this work
  • National University of Singapore
  • Zhejiang University

Research output: Contribution to journalArticlepeer-review

Abstract

Brillouin light scattering from several aggregates of monodisperse Ge O2 nanocubes has been measured. Six well-resolved spectral peaks are observed whose frequencies scale as 1L, where L is the cube edge length. A finite element analysis of the eigenvibrations of a free nanocube reveals that the peaks are due to acoustic phonon confinement. Simulations show that the lowest-energy mode has a predominantly torsionallike character. The elastic constants of the nanocubes are found to be much lower than those of bulk Ge O2.

Original languageEnglish
Article number093116
JournalApplied Physics Letters
Volume91
Issue number9
DOIs
StatePublished - 2007
Externally publishedYes

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