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Effect of long-term room-temperature storage on the structure and properties of glassy melt-spun Mg-Al-Ca alloys

  • M. S. Ong*
  • , W. M. Rainforth
  • , Y. Li
  • , H. Jones
  • *Corresponding author for this work
  • National University of Singapore
  • University of Sheffield

Research output: Contribution to journalArticlepeer-review

Abstract

The effects of 48 months storage at room temperature on the structure and properties of glassy melt-spun Mg-Al-Ca alloys has been determined. The results show that while Knoop hardness does not differ significantly from values obtained shortly after melt spinning, x-ray diffraction (XRD) shows considerably stronger signals from αMg present in the glassy matrix, detected only for the most dilute glass forming composition some months after melt spinning. High-resolution electron microscopy (HREM) studies show the presence of nanocrystallites in the glassy matrix with interplanar spacings matching αMg, and energy-dispersive spectroscopy (EDS) indicates the presence of Al and Ca within these nanocrystallites. Differential scanning calorimetry (DSC) studies at 20, 40, and 80 K/min show evidence of two-stage crystallization with the first stage starting at approximately 120 deg with a peak at approximately 150 °C and the second stage peaking at approximately 250 °C. The significance of these results is discussed.

Original languageEnglish
Pages (from-to)2155-2162
Number of pages8
JournalMetallurgical and Materials Transactions A: Physical Metallurgy and Materials Science
Volume31
Issue number9
DOIs
StatePublished - 2000
Externally publishedYes

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