Fluorescence regulation derived from Eu3+in miscible-order fluoride-phosphate blocky phosphor

Jianyang Xiong; Gang Li; Jing Zhang; Desheng Li; Edwin Yue Bun Pun; Hai Lin

doi:10.1088/1361-6528/ac15c7

Fluorescence regulation derived from Eu³⁺in miscible-order fluoride-phosphate blocky phosphor

Jianyang Xiong
, Gang Li
, Jing Zhang
, Desheng Li^*
, Edwin Yue Bun Pun
, Hai Lin^*

^*Corresponding author for this work

Dalian Polytechnic University
CAS - Dalian Institute of Chemical Physics
City University of Hong Kong

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Miscible-order fluoride-phosphate blocky phosphor (FBP), composed with ordered-phase of NaYF4 crystals and unordered phase of tin-fluorophosphate glass, is prepared by a two-step process and luminescent properties of FBPs embedded with different particle sizes of NaYF4 crystals are presented. High-frequency fluorescence from higher metastable 5DJ (J = 1, 2 and 3) energy levels are effectively released in Eu3+ doped fluoride crystals. Taking the blue emission of Sn2+ as the framework, multi-peak emissions from metastable energy levels are controlled to adjust the color coordinates of the FBP to the white-light region, which the color rendering index (CRI) reaches 89. Tunable color FBP with high CRI retains splendid luminescence property of fluoride, providing a potential candidate for the development of white LED.

Original language	English
Article number	435705
Journal	Nanotechnology
Volume	32
Issue number	43
DOIs	https://doi.org/10.1088/1361-6528/ac15c7
State	Published - 22 Oct 2021
Externally published	Yes

Keywords

Fluoride-phosphate blocky phosphor
Multi-peak emissions
White-light-emitting

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10.1088/1361-6528/ac15c7

Cite this

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title = "Fluorescence regulation derived from Eu3+in miscible-order fluoride-phosphate blocky phosphor",

abstract = "Miscible-order fluoride-phosphate blocky phosphor (FBP), composed with ordered-phase of NaYF4 crystals and unordered phase of tin-fluorophosphate glass, is prepared by a two-step process and luminescent properties of FBPs embedded with different particle sizes of NaYF4 crystals are presented. High-frequency fluorescence from higher metastable 5DJ (J = 1, 2 and 3) energy levels are effectively released in Eu3+ doped fluoride crystals. Taking the blue emission of Sn2+ as the framework, multi-peak emissions from metastable energy levels are controlled to adjust the color coordinates of the FBP to the white-light region, which the color rendering index (CRI) reaches 89. Tunable color FBP with high CRI retains splendid luminescence property of fluoride, providing a potential candidate for the development of white LED.",

keywords = "Fluoride-phosphate blocky phosphor, Multi-peak emissions, White-light-emitting",

author = "Jianyang Xiong and Gang Li and Jing Zhang and Desheng Li and Pun, \{Edwin Yue Bun\} and Hai Lin",

note = "Publisher Copyright: {\textcopyright} 2021 IOP Publishing Ltd.",

year = "2021",

month = oct,

day = "22",

doi = "10.1088/1361-6528/ac15c7",

language = "英语",

volume = "32",

journal = "Nanotechnology",

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number = "43",

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TY - JOUR

T1 - Fluorescence regulation derived from Eu3+in miscible-order fluoride-phosphate blocky phosphor

AU - Xiong, Jianyang

AU - Li, Gang

AU - Zhang, Jing

AU - Li, Desheng

AU - Pun, Edwin Yue Bun

AU - Lin, Hai

PY - 2021/10/22

Y1 - 2021/10/22

N2 - Miscible-order fluoride-phosphate blocky phosphor (FBP), composed with ordered-phase of NaYF4 crystals and unordered phase of tin-fluorophosphate glass, is prepared by a two-step process and luminescent properties of FBPs embedded with different particle sizes of NaYF4 crystals are presented. High-frequency fluorescence from higher metastable 5DJ (J = 1, 2 and 3) energy levels are effectively released in Eu3+ doped fluoride crystals. Taking the blue emission of Sn2+ as the framework, multi-peak emissions from metastable energy levels are controlled to adjust the color coordinates of the FBP to the white-light region, which the color rendering index (CRI) reaches 89. Tunable color FBP with high CRI retains splendid luminescence property of fluoride, providing a potential candidate for the development of white LED.

AB - Miscible-order fluoride-phosphate blocky phosphor (FBP), composed with ordered-phase of NaYF4 crystals and unordered phase of tin-fluorophosphate glass, is prepared by a two-step process and luminescent properties of FBPs embedded with different particle sizes of NaYF4 crystals are presented. High-frequency fluorescence from higher metastable 5DJ (J = 1, 2 and 3) energy levels are effectively released in Eu3+ doped fluoride crystals. Taking the blue emission of Sn2+ as the framework, multi-peak emissions from metastable energy levels are controlled to adjust the color coordinates of the FBP to the white-light region, which the color rendering index (CRI) reaches 89. Tunable color FBP with high CRI retains splendid luminescence property of fluoride, providing a potential candidate for the development of white LED.

KW - Fluoride-phosphate blocky phosphor

KW - Multi-peak emissions

KW - White-light-emitting

UR - https://www.scopus.com/pages/publications/85113713780

U2 - 10.1088/1361-6528/ac15c7

DO - 10.1088/1361-6528/ac15c7

M3 - 文章

C2 - 34280909

AN - SCOPUS:85113713780

SN - 0957-4484

VL - 32

JO - Nanotechnology

JF - Nanotechnology

IS - 43

M1 - 435705

ER -

Fluorescence regulation derived from Eu³⁺in miscible-order fluoride-phosphate blocky phosphor

Abstract

Keywords

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