Infrequent blue and green emission transitions from Eu3+ in heavy metal tellurite glasses with low phonon energy

H. Lin; S. Tanabe; L. Lin; D. L. Yang; K. Liu; W. H. Wong; J. Y. Yu; E. Y.B. Pun

doi:10.1016/j.physleta.2006.05.066

Infrequent blue and green emission transitions from Eu³⁺ in heavy metal tellurite glasses with low phonon energy

H. Lin^*
, S. Tanabe
, L. Lin
, D. L. Yang
, K. Liu
, W. H. Wong
, J. Y. Yu
, E. Y.B. Pun

^*Corresponding author for this work

Dalian Polytechnic University
Kyoto University
Dalian Medical University
City University of Hong Kong

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Eu³⁺ doped alkali-barium-bismuth-tellurite (Eu³⁺:LKBBT) glasses were prepared by conventional melt quenching. Twelve emission bands including infrequent blue and green bands are observed and they almost cover whole visible spectral region under violet light radiation. The blue and green emissions of Eu³⁺ rarely appeared in oxide glasses before, but they have been clearly recorded in Eu³⁺:LKBBT glasses even in the case of high concentration doping of Eu³⁺. The analysis based on spontaneous-radiative rate, energy gap and Raman scattering reveals that the obtaining of the abundant multichannel emissions of Eu³⁺ is due to the higher refractive index and the lower phonon energy in LKBBT glass system.

Original language	English
Pages (from-to)	474-477
Number of pages	4
Journal	Physics Letters, Section A: General, Atomic and Solid State Physics
Volume	358
Issue number	5-6
DOIs	https://doi.org/10.1016/j.physleta.2006.05.066
State	Published - 30 Oct 2006
Externally published	Yes

Keywords

Blue and green emissions
Europium
Heavy metal tellurite glasses

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10.1016/j.physleta.2006.05.066

Cite this

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title = "Infrequent blue and green emission transitions from Eu3+ in heavy metal tellurite glasses with low phonon energy",

abstract = "Eu3+ doped alkali-barium-bismuth-tellurite (Eu3+:LKBBT) glasses were prepared by conventional melt quenching. Twelve emission bands including infrequent blue and green bands are observed and they almost cover whole visible spectral region under violet light radiation. The blue and green emissions of Eu3+ rarely appeared in oxide glasses before, but they have been clearly recorded in Eu3+:LKBBT glasses even in the case of high concentration doping of Eu3+. The analysis based on spontaneous-radiative rate, energy gap and Raman scattering reveals that the obtaining of the abundant multichannel emissions of Eu3+ is due to the higher refractive index and the lower phonon energy in LKBBT glass system.",

keywords = "Blue and green emissions, Europium, Heavy metal tellurite glasses",

author = "H. Lin and S. Tanabe and L. Lin and Yang, \{D. L.\} and K. Liu and Wong, \{W. H.\} and Yu, \{J. Y.\} and Pun, \{E. Y.B.\}",

year = "2006",

month = oct,

day = "30",

doi = "10.1016/j.physleta.2006.05.066",

language = "英语",

volume = "358",

pages = "474--477",

journal = "Physics Letters, Section A: General, Atomic and Solid State Physics",

issn = "0375-9601",

publisher = "Elsevier B.V.",

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}

TY - JOUR

T1 - Infrequent blue and green emission transitions from Eu3+ in heavy metal tellurite glasses with low phonon energy

AU - Lin, H.

AU - Tanabe, S.

AU - Lin, L.

AU - Yang, D. L.

AU - Liu, K.

AU - Wong, W. H.

AU - Yu, J. Y.

AU - Pun, E. Y.B.

PY - 2006/10/30

Y1 - 2006/10/30

N2 - Eu3+ doped alkali-barium-bismuth-tellurite (Eu3+:LKBBT) glasses were prepared by conventional melt quenching. Twelve emission bands including infrequent blue and green bands are observed and they almost cover whole visible spectral region under violet light radiation. The blue and green emissions of Eu3+ rarely appeared in oxide glasses before, but they have been clearly recorded in Eu3+:LKBBT glasses even in the case of high concentration doping of Eu3+. The analysis based on spontaneous-radiative rate, energy gap and Raman scattering reveals that the obtaining of the abundant multichannel emissions of Eu3+ is due to the higher refractive index and the lower phonon energy in LKBBT glass system.

AB - Eu3+ doped alkali-barium-bismuth-tellurite (Eu3+:LKBBT) glasses were prepared by conventional melt quenching. Twelve emission bands including infrequent blue and green bands are observed and they almost cover whole visible spectral region under violet light radiation. The blue and green emissions of Eu3+ rarely appeared in oxide glasses before, but they have been clearly recorded in Eu3+:LKBBT glasses even in the case of high concentration doping of Eu3+. The analysis based on spontaneous-radiative rate, energy gap and Raman scattering reveals that the obtaining of the abundant multichannel emissions of Eu3+ is due to the higher refractive index and the lower phonon energy in LKBBT glass system.

KW - Blue and green emissions

KW - Europium

KW - Heavy metal tellurite glasses

UR - https://www.scopus.com/pages/publications/33748169643

U2 - 10.1016/j.physleta.2006.05.066

DO - 10.1016/j.physleta.2006.05.066

M3 - 文章

AN - SCOPUS:33748169643

SN - 0375-9601

VL - 358

SP - 474

EP - 477

JO - Physics Letters, Section A: General, Atomic and Solid State Physics

JF - Physics Letters, Section A: General, Atomic and Solid State Physics

IS - 5-6

ER -

Infrequent blue and green emission transitions from Eu³⁺ in heavy metal tellurite glasses with low phonon energy

Abstract

Keywords

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