Multiplier effect of sensitization for Dy3+ fluorescence in borosilicate glass phosphor

H. Zhang; P. J. Lin; J. L. Yuan; E. Y.B. Pun; D. S. Li; H. Lin

doi:10.1016/j.jlumin.2020.117062

Multiplier effect of sensitization for Dy³⁺ fluorescence in borosilicate glass phosphor

H. Zhang
, P. J. Lin
, J. L. Yuan
, E. Y.B. Pun
, D. S. Li
, H. Lin^*

^*Corresponding author for this work

Dalian Polytechnic University
Ningbo University
City University of Hong Kong

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Based on the demonstration of the fluorescent properties, Dy³⁺ doped borosilicate glasses (NLKSB) were confirmed to be an efficient phosphor under long-wave ultraviolet (UVA) radiation. Ce³⁺ and Sb³⁺ are introduced to the Dy³⁺ doped NLKSB glass system, which extends the excitable region to medium-wave ultraviolet (UVB) and short-wave ultraviolet (UVC) spectral ranges. Sensitization coefficient of Ce³⁺-Sb³⁺ to Dy³⁺ under different wavelengths is in accordance with the multiplication of Ce³⁺ to Dy³⁺ and Sb³⁺ to Dy³⁺, besides, this unexpected phenomenon is attributed to the effect of band superposition. The enhancement coefficient of quantum yield reaches up to 7.03 for the main emission of Dy³⁺ under the UVB-LED excitation, which indicates that multiplier effect of sensitization plays an outstanding role in macroscopic applications. The excellent sensitization effect and the effective excitability expansion provide a breakthrough in developing of high-quality lighting devices.

Original language	English
Article number	117062
Journal	Journal of Luminescence
Volume	221
DOIs	https://doi.org/10.1016/j.jlumin.2020.117062
State	Published - May 2020
Externally published	Yes

Keywords

Borosilicate glasses
Dy fluorescence
Multiplier effect of sensitization
UV excitation-extension

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10.1016/j.jlumin.2020.117062

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@article{1f176031bb9f4fa0a6a28403486e06cb,

title = "Multiplier effect of sensitization for Dy3+ fluorescence in borosilicate glass phosphor",

abstract = "Based on the demonstration of the fluorescent properties, Dy3+ doped borosilicate glasses (NLKSB) were confirmed to be an efficient phosphor under long-wave ultraviolet (UVA) radiation. Ce3+ and Sb3+ are introduced to the Dy3+ doped NLKSB glass system, which extends the excitable region to medium-wave ultraviolet (UVB) and short-wave ultraviolet (UVC) spectral ranges. Sensitization coefficient of Ce3+-Sb3+ to Dy3+ under different wavelengths is in accordance with the multiplication of Ce3+ to Dy3+ and Sb3+ to Dy3+, besides, this unexpected phenomenon is attributed to the effect of band superposition. The enhancement coefficient of quantum yield reaches up to 7.03 for the main emission of Dy3+ under the UVB-LED excitation, which indicates that multiplier effect of sensitization plays an outstanding role in macroscopic applications. The excellent sensitization effect and the effective excitability expansion provide a breakthrough in developing of high-quality lighting devices.",

keywords = "Borosilicate glasses, Dy fluorescence, Multiplier effect of sensitization, UV excitation-extension",

author = "H. Zhang and Lin, \{P. J.\} and Yuan, \{J. L.\} and Pun, \{E. Y.B.\} and Li, \{D. S.\} and H. Lin",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2020",

month = may,

doi = "10.1016/j.jlumin.2020.117062",

language = "英语",

volume = "221",

journal = "Journal of Luminescence",

issn = "0022-2313",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Multiplier effect of sensitization for Dy3+ fluorescence in borosilicate glass phosphor

AU - Zhang, H.

AU - Lin, P. J.

AU - Yuan, J. L.

AU - Pun, E. Y.B.

AU - Li, D. S.

AU - Lin, H.

PY - 2020/5

Y1 - 2020/5

N2 - Based on the demonstration of the fluorescent properties, Dy3+ doped borosilicate glasses (NLKSB) were confirmed to be an efficient phosphor under long-wave ultraviolet (UVA) radiation. Ce3+ and Sb3+ are introduced to the Dy3+ doped NLKSB glass system, which extends the excitable region to medium-wave ultraviolet (UVB) and short-wave ultraviolet (UVC) spectral ranges. Sensitization coefficient of Ce3+-Sb3+ to Dy3+ under different wavelengths is in accordance with the multiplication of Ce3+ to Dy3+ and Sb3+ to Dy3+, besides, this unexpected phenomenon is attributed to the effect of band superposition. The enhancement coefficient of quantum yield reaches up to 7.03 for the main emission of Dy3+ under the UVB-LED excitation, which indicates that multiplier effect of sensitization plays an outstanding role in macroscopic applications. The excellent sensitization effect and the effective excitability expansion provide a breakthrough in developing of high-quality lighting devices.

AB - Based on the demonstration of the fluorescent properties, Dy3+ doped borosilicate glasses (NLKSB) were confirmed to be an efficient phosphor under long-wave ultraviolet (UVA) radiation. Ce3+ and Sb3+ are introduced to the Dy3+ doped NLKSB glass system, which extends the excitable region to medium-wave ultraviolet (UVB) and short-wave ultraviolet (UVC) spectral ranges. Sensitization coefficient of Ce3+-Sb3+ to Dy3+ under different wavelengths is in accordance with the multiplication of Ce3+ to Dy3+ and Sb3+ to Dy3+, besides, this unexpected phenomenon is attributed to the effect of band superposition. The enhancement coefficient of quantum yield reaches up to 7.03 for the main emission of Dy3+ under the UVB-LED excitation, which indicates that multiplier effect of sensitization plays an outstanding role in macroscopic applications. The excellent sensitization effect and the effective excitability expansion provide a breakthrough in developing of high-quality lighting devices.

KW - Borosilicate glasses

KW - Dy fluorescence

KW - Multiplier effect of sensitization

KW - UV excitation-extension

UR - https://www.scopus.com/pages/publications/85078500968

U2 - 10.1016/j.jlumin.2020.117062

DO - 10.1016/j.jlumin.2020.117062

M3 - 文章

AN - SCOPUS:85078500968

SN - 0022-2313

VL - 221

JO - Journal of Luminescence

JF - Journal of Luminescence

M1 - 117062

ER -

Multiplier effect of sensitization for Dy³⁺ fluorescence in borosilicate glass phosphor

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Keywords

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