S⋯Cl intramolecular interaction: An efficient strategy to improve power conversion efficiency of organic solar cells

Sai Jiang; Linqing Qin; Hao Chen; Xiaoxi Wu; Yuhao Li; Lei Lv; Jingya Chen; Youtian Tao; Shiming Zhang; Xinhui Lu; Qinqin Shi; Hui Huang

doi:10.1016/j.dyepig.2020.108416

S⋯Cl intramolecular interaction: An efficient strategy to improve power conversion efficiency of organic solar cells

Sai Jiang
, Linqing Qin
, Hao Chen
, Xiaoxi Wu
, Yuhao Li
, Lei Lv
, Jingya Chen
, Youtian Tao
, Shiming Zhang
, Xinhui Lu
, Qinqin Shi
, Hui Huang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Noncovalent conformational locks (NCLs) including S⋯N, Se⋯O, and S⋯O etc. Have been an effective strategy to improve the planarity and rigidity, and charge transport mobility of organic/polymeric semiconductors. Herein, by replacing methyl group (ITMIC) with chlorine (ITCIC) in the π-bridge, the planarity and rigidity of the π-conjugated skeleton was enhanced by introduction of S⋯Cl NCLs, thus the charge transport mobility was improved accordingly. As a result, PM6:ITCIC based organic solar cells showed impressive PCE of 11.34%, much higher than that based on PM6:ITMIC. This contribution demonstrated a novel kind NCLs (S⋯Cl) for improving the performance of organic solar cells.

Original language	English
Article number	108416
Journal	Dyes and Pigments
Volume	179
DOIs	https://doi.org/10.1016/j.dyepig.2020.108416
State	Published - Aug 2020
Externally published	Yes

Keywords

Charge transport mobility
Non-fullerene acceptor
Noncovalent conformational locks
Organic solar cells

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10.1016/j.dyepig.2020.108416

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@article{2da5385395b540b685e7fad10a405ec4,

title = "S⋯Cl intramolecular interaction: An efficient strategy to improve power conversion efficiency of organic solar cells",

abstract = "Noncovalent conformational locks (NCLs) including S⋯N, Se⋯O, and S⋯O etc. Have been an effective strategy to improve the planarity and rigidity, and charge transport mobility of organic/polymeric semiconductors. Herein, by replacing methyl group (ITMIC) with chlorine (ITCIC) in the π-bridge, the planarity and rigidity of the π-conjugated skeleton was enhanced by introduction of S⋯Cl NCLs, thus the charge transport mobility was improved accordingly. As a result, PM6:ITCIC based organic solar cells showed impressive PCE of 11.34\%, much higher than that based on PM6:ITMIC. This contribution demonstrated a novel kind NCLs (S⋯Cl) for improving the performance of organic solar cells.",

keywords = "Charge transport mobility, Non-fullerene acceptor, Noncovalent conformational locks, Organic solar cells",

author = "Sai Jiang and Linqing Qin and Hao Chen and Xiaoxi Wu and Yuhao Li and Lei Lv and Jingya Chen and Youtian Tao and Shiming Zhang and Xinhui Lu and Qinqin Shi and Hui Huang",

note = "Publisher Copyright: {\textcopyright} 2020",

year = "2020",

month = aug,

doi = "10.1016/j.dyepig.2020.108416",

language = "英语",

volume = "179",

journal = "Dyes and Pigments",

issn = "0143-7208",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - S⋯Cl intramolecular interaction

T2 - An efficient strategy to improve power conversion efficiency of organic solar cells

AU - Jiang, Sai

AU - Qin, Linqing

AU - Chen, Hao

AU - Wu, Xiaoxi

AU - Li, Yuhao

AU - Lv, Lei

AU - Chen, Jingya

AU - Tao, Youtian

AU - Zhang, Shiming

AU - Lu, Xinhui

AU - Shi, Qinqin

AU - Huang, Hui

PY - 2020/8

Y1 - 2020/8

N2 - Noncovalent conformational locks (NCLs) including S⋯N, Se⋯O, and S⋯O etc. Have been an effective strategy to improve the planarity and rigidity, and charge transport mobility of organic/polymeric semiconductors. Herein, by replacing methyl group (ITMIC) with chlorine (ITCIC) in the π-bridge, the planarity and rigidity of the π-conjugated skeleton was enhanced by introduction of S⋯Cl NCLs, thus the charge transport mobility was improved accordingly. As a result, PM6:ITCIC based organic solar cells showed impressive PCE of 11.34%, much higher than that based on PM6:ITMIC. This contribution demonstrated a novel kind NCLs (S⋯Cl) for improving the performance of organic solar cells.

AB - Noncovalent conformational locks (NCLs) including S⋯N, Se⋯O, and S⋯O etc. Have been an effective strategy to improve the planarity and rigidity, and charge transport mobility of organic/polymeric semiconductors. Herein, by replacing methyl group (ITMIC) with chlorine (ITCIC) in the π-bridge, the planarity and rigidity of the π-conjugated skeleton was enhanced by introduction of S⋯Cl NCLs, thus the charge transport mobility was improved accordingly. As a result, PM6:ITCIC based organic solar cells showed impressive PCE of 11.34%, much higher than that based on PM6:ITMIC. This contribution demonstrated a novel kind NCLs (S⋯Cl) for improving the performance of organic solar cells.

KW - Charge transport mobility

KW - Non-fullerene acceptor

KW - Noncovalent conformational locks

KW - Organic solar cells

UR - https://www.scopus.com/pages/publications/85082850222

U2 - 10.1016/j.dyepig.2020.108416

DO - 10.1016/j.dyepig.2020.108416

M3 - 文章

AN - SCOPUS:85082850222

SN - 0143-7208

VL - 179

JO - Dyes and Pigments

JF - Dyes and Pigments

M1 - 108416

ER -

S⋯Cl intramolecular interaction: An efficient strategy to improve power conversion efficiency of organic solar cells

Abstract

Keywords

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